Steel is an alloy made by combining iron and another element, usually carbon. When carbon is used, its content in the steel is between 0.2% and 2.1% by weight, depending on the grade. Other alloying elements sometimes used are manganese, chromium, vanadium and tungsten.[1] Carbon and other elements act as a hardening agent, preventing dislocations in the iron atom crystal lattice from sliding past one another. Varying the amount of alloying elements and the form of their presence in the steel (solute elements, precipitated phase) controls qualities such as the hardness, ductility, and tensile strength of the resulting steel. Steel with increased carbon content can be made harder and stronger than iron, but such steel is also less ductile than iron.
Alloys with a higher than 2.1% carbon content are known as cast iron because of their lower melting point and good castability.[1] Steel is also distinguishable from wrought iron, which can contain a small amount of carbon, but it is included in the form of slag inclusions. Two distinguishing factors are steel's increased rust resistance and better weldability.
Though steel had been produced by various inefficient methods long before the Renaissance, its use became more common after more efficient production methods were devised in the 17th century. With the invention of the Bessemer process in the mid-19th century, steel became an inexpensive mass-produced material. Further refinements in the process, such as basic oxygen steelmaking (BOS), lowered the cost of production while increasing the quality of the metal. Today, steel is one of the most common materials in the world, with more than 1.3 billion tons produced annually. It is a major component in buildings, infrastructure, tools, ships, automobiles, machines, appliances, and weapons. Modern steel is generally identified by various grades defined by assorted standards organizations.
Iron-carbon
phase diagram, showing the conditions necessary to form different phases
Iron is found in the Earth's crust only in the form of an ore, usually an iron oxide, such as magnetite, hematite etc. Iron is extracted from iron ore by removing the oxygen and combining the ore with a preferred chemical partner such as carbon. This process, known as smelting, was first applied to metals with lower melting points, such as tin, which melts at approximately 250 °C (482 °F) and copper, which melts at approximately 1,100 °C (2,010 °F). In comparison, cast iron melts at approximately 1,375 °C (2,507 °F). All of these temperatures could be reached with ancient methods that have been used since the Bronze Age. Since the oxidation rate itself increases rapidly beyond 800 °C (1,470 °F), it is important that smelting take place in a low-oxygen environment. Unlike copper and tin, liquid iron dissolves carbon quite readily. Smelting results in an alloy (pig iron) containing too much carbon to be called steel.[2] The excess carbon and other impurities are removed in a subsequent step.
Other materials are often added to the iron/carbon mixture to produce steel with desired properties. Nickel and manganese in steel add to its tensile strength and make austenite more chemically stable, chromium increases hardness and melting temperature, and vanadium also increases hardness while reducing the effects of metal fatigue. To prevent corrosion, at least 11% chromium is added to steel so that a hard oxide forms on the metal surface; this is known as stainless steel. Tungsten interferes with the formation of cementite, allowing martensite to form with slower quench rates, resulting in high speed steel. On the other hand, sulfur, nitrogen, and phosphorus make steel more brittle, so these commonly found elements must be removed from the ore during processing.[3]
The density of steel varies based on the alloying constituents but usually ranges between 7,750 and 8,050 kg/m3 (484 and 503 lb/cu ft), or 7.75 and 8.05 g/cm3 (4.48 and 4.65 oz/cu in).[4]
Even in the narrow range of concentrations which make up steel, mixtures of carbon and iron can form a number of different structures, with very different properties. Understanding such properties is essential to making quality steel. At room temperature, the most stable form of iron is the body-centered cubic (BCC) structure α-ferrite. It is a fairly soft metallic material that can dissolve only a small concentration of carbon, no more than 0.021 wt% at 723 °C (1,333 °F), and only 0.005% at 0 °C (32 °F). If steel contains more than 0.021% carbon at steelmaking temperatures then it transforms into a face-centered cubic (FCC) structure, called austenite or γ-iron. It is also soft and metallic but can dissolve considerably more carbon, as much as 2.1%[5] carbon at 1,148 °C (2,098 °F), which reflects the upper carbon content of steel.[6]
When steels with less than 0.8% carbon, known as a hypoeutectoid steel, are cooled from an austenitic phase the mixture attempts to revert to the ferrite phase, resulting in an excess of carbon. One way for carbon to leave the austenite is for cementite to precipitate out of the mix, leaving behind iron that is pure enough to take the form of ferrite, resulting in a cementite-ferrite mixture. Cementite is a hard and brittle intermetallic compound with the chemical formula of Fe3C. At the eutectoid, 0.8% carbon, the cooled structure takes the form of pearlite, named after its resemblance to mother of pearl. For steels that have more than 0.8% carbon the cooled structure takes the form of pearlite and cementite.[7]
Perhaps the most important polymorphic form is martensite, a metastable phase which is significantly stronger than other steel phases. When the steel is in an austenitic phase and then quenched it forms into martensite, because the atoms "freeze" in place when the cell structure changes from FCC to BCC. Depending on the carbon content the martensitic phase takes different forms. Below approximately 0.2% carbon it takes an α ferrite BCC crystal form, but higher carbon contents take a body-centered tetragonal (BCT) structure. There is no thermal activation energy for the transformation from austenite to martensite. Moreover, there is no compositional change so the atoms generally retain their same neighbors.[8]
Martensite has a lower density than austenite does, so that transformation between them results in a change of volume. In this case, expansion occurs. Internal stresses from this expansion generally take the form of compression on the crystals of martensite and tension on the remaining ferrite, with a fair amount of shear on both constituents. If quenching is done improperly, the internal stresses can cause a part to shatter as it cools. At the very least, they cause internal work hardening and other microscopic imperfections. It is common for quench cracks to form when water quenched, although they may not always be visible.[9]
There are many types of heat treating processes available to steel. The most common are annealing and quenching and tempering. Annealing is the process of heating the steel to a sufficiently high temperature to soften it. This process occurs through three phases: recovery, recrystallization, and grain growth. The temperature required to anneal steel depends on the type of annealing and the constituents of the alloy.[10]
Quenching and tempering first involves heating the steel to the austenite phase, then quenching it in water or oil. This rapid cooling results in a hard and brittle martensitic structure.[8] The steel is then tempered, which is just a specialized type of annealing. In this application the annealing (tempering) process transforms some of the martensite into cementite, or spheroidite to reduce internal stresses and defects, which ultimately results in a more ductile and fracture-resistant metal.[11]
Iron ore pellets for the production of steel
Main article:
SteelmakingWhen iron is smelted from its ore by commercial processes, it contains more carbon than is desirable. To become steel, it must be melted and reprocessed to reduce the carbon to the correct amount, at which point other elements can be added. This liquid is then continuously cast into long slabs or cast into ingots. Approximately 96% of steel is continuously cast, while only 4% is produced as cast steel ingots.[12] The ingots are then heated in a soaking pit and hot rolled into slabs, blooms, or billets. Slabs are hot or cold rolled into sheet metal or plates. Billets are hot or cold rolled into bars, rods, and wire. Blooms are hot or cold rolled into structural steel, such as I-beams and rails. In modern foundries these processes often occur in one assembly line, with ore coming in and finished steel coming out.[13] Sometimes after a steel's final rolling it is heat treated for strength, however this is relatively rare.[14]
Steel was known in antiquity, and may have been produced by managing bloomeries, or iron-smelting facilities, in which the bloom contained carbon.[15]
The earliest known production of steel is a piece of ironware excavated from an archaeological site in Anatolia (Kaman-Kalehoyuk) and is about 4,000 years old.[16] Other ancient steel comes from East Africa, dating back to 1400 BC.[17] In the 4th century BC steel weapons like the Falcata were produced in the Iberian Peninsula, while Noric steel was used by the Roman military.[18] The Chinese of the Warring States (403–221 BC) had quench-hardened steel,[19] while Chinese of the Han Dynasty (202 BC – 220 AD) created steel by melting together wrought iron with cast iron, gaining an ultimate product of a carbon-intermediate steel by the 1st century AD.[20][21] The Haya people of East Africa invented a type of high-heat blast furnace which allowed them to forge carbon steel at 1,802 °C (3,276 °F) nearly 2,000 years ago.[22]
Evidence of the earliest production of high carbon steel in the Indian Subcontinent was found in Samanalawewa area in Sri Lanka.[23] Wootz steel was produced in India by about 300 BC.[24] Along with their original methods of forging steel, the Chinese had also adopted the production methods of creating Wootz steel, an idea imported into China from India by the 5th century AD.[25] In Sri Lanka, this early steel-making method employed the unique use of a wind furnace, blown by the monsoon winds, that was capable of producing high-carbon steel.[26] Also known as Damascus steel, wootz is famous for its durability and ability to hold an edge. It was originally created from a number of different materials including various trace elements. It was essentially a complicated alloy with iron as its main component. Recent studies have suggested that carbon nanotubes were included in its structure, which might explain some of its legendary qualities, though given the technology available at that time, they were produced by chance rather than by design.[27] Natural wind was used where the soil containing iron was heated up with the use of wood. The ancient Sinhalese managed to extract a ton of steel for every 2 tons of soil[citation needed], a remarkable feat at the time. One such furnace was found in Samanalawewa and archaeologists were able to produce steel as the ancients did long ago.[26][28]
Crucible steel, formed by slowly heating and cooling pure iron and carbon (typically in the form of charcoal) in a crucible, was produced in Merv by the 9th to 10th century AD.[24] In the 11th century, there is evidence of the production of steel in Song China using two techniques: a "berganesque" method that produced inferior, inhomogeneous steel and a precursor to the modern Bessemer process that used partial decarbonization via repeated forging under a cold blast.[29]
Since the 17th century the first step in European steel production has been the smelting of iron ore into pig iron in a blast furnace.[30] Originally using charcoal, modern methods use coke, which has proven to be a great deal cheaper.[31][32][33]
In these processes pig iron was "fined" in a finery forge to produce bar iron (wrought iron), which was then used in steel-making.[30]
The production of steel by the cementation process was described in a treatise published in Prague in 1574 and was in use in Nuremberg from 1601. A similar process for case hardening armour and files was described in a book published in Naples in 1589. The process was introduced to England in about 1614.[34] It was produced by Sir Basil Brooke at Coalbrookdale during the 1610s. The raw material for this were bars of wrought iron. During the 17th century it was realised that the best steel came from oregrounds iron from a region of Sweden, north of Stockholm. This was still the usual raw material in the 19th century, almost as long as the process was used.[35][36]
Crucible steel is steel that has been melted in a crucible rather than being forged, with the result that it is more homogeneous. Most previous furnaces could not reach high enough temperatures to melt the steel. The early modern crucible steel industry resulted from the invention of Benjamin Huntsman in the 1740s. Blister steel (made as above) was melted in a crucible or in a furnace, and cast (usually) into ingots.[36][37]
A Siemens-Martin steel oven from the
Brandenburg Museum of Industry
White-hot steel pouring out of an electric arc furnace
The modern era in steelmaking began with the introduction of Henry Bessemer's Bessemer process in 1858. His raw material was pig iron.[38] This enabled steel to be produced in large quantities cheaply, thus mild steel is now used for most purposes for which wrought iron was formerly used.[39] The Gilchrist-Thomas process (or basic Bessemer process) was an improvement to the Bessemer process, lining the converter with a basic material to remove phosphorus. Another improvement in steelmaking was the Siemens-Martin process, which complemented the Bessemer process.[36]
These were rendered obsolete by the Linz-Donawitz process of basic oxygen steelmaking (BOS), developed in the 1950s, and other oxygen steelmaking processes. Basic oxygen steelmaking is superior to previous steelmaking methods because the oxygen pumped into the furnace limits impurities.[40] Now, electric arc furnaces (EAF) are a common method of reprocessing scrap metal to create new steel. They can also be used for converting pig iron to steel, but they use a lot of electricity (about 440 kWh per metric ton), and are thus generally only economical when there is a plentiful supply of cheap electricity.[41]
Steel production by country in 2007
It is common today to talk about "the iron and steel industry" as if it were a single entity, but historically they were separate products. The steel industry is often considered to be an indicator of economic progress, because of the critical role played by steel in infrastructural and overall economic development.[42]
In 1980, there were more than 500,000 U.S. steelworkers. By 2000, the number of steelworkers fell to 224,000.[43]
The economic boom in China and India has caused a massive increase in the demand for steel in recent years. Between 2000 and 2005, world steel demand increased by 6%. Since 2000, several Indian [44] and Chinese steel firms have risen to prominence like Tata Steel (which bought Corus Group in 2007), Shanghai Baosteel Group Corporation and Shagang Group. ArcelorMittal is however the world's largest steel producer.
In 2005, the British Geological Survey stated China was the top steel producer with about one-third of the world share; Japan, Russia, and the US followed respectively.[45]
In 2008, steel began trading as a commodity on the London Metal Exchange. At the end of 2008, the steel industry faced a sharp downturn that led to many cut-backs.[46]
Modern steels are made with varying combinations of alloy metals to fulfill many purposes.[3] Carbon steel, composed simply of iron and carbon, accounts for 90% of steel production.[1] High strength low alloy steel has small additions (usually < 2% by weight) of other elements, typically 1.5% manganese, to provide additional strength for a modest price increase.[47] Low alloy steel is alloyed with other elements, usually molybdenum, manganese, chromium, or nickel, in amounts of up to 10% by weight to improve the hardenability of thick sections.[1] Stainless steels and surgical stainless steels contain a minimum of 11% chromium, often combined with nickel, to resist corrosion (rust). Some stainless steels, such as the ferritic stainless steels are magnetic, while others, such as the austenitic, are nonmagnetic.[48]
Some more modern steels include tool steels, which are alloyed with large amounts of tungsten and cobalt or other elements to maximize solution hardening. This also allows the use of precipitation hardening and improves the alloy's temperature resistance.[1] Tool steel is generally used in axes, drills, and other devices that need a sharp, long-lasting cutting edge. Other special-purpose alloys include weathering steels such as Cor-ten, which weather by acquiring a stable, rusted surface, and so can be used un-painted.[49]
Many other high-strength alloys exist, such as dual-phase steel, which is heat treated to contain both a ferritic and martensitic microstructure for extra strength.[50] Transformation Induced Plasticity (TRIP) steel involves special alloying and heat treatments to stabilize amounts of austentite at room temperature in normally austentite-free low-alloy ferritic steels. By applying strain to the metal, the austentite undergoes a phase transition to martensite without the addition of heat.[51] Maraging steel is alloyed with nickel and other elements, but unlike most steel contains almost no carbon at all. This creates a very strong but still malleable metal.[52] Twinning Induced Plasticity (TWIP) steel uses a specific type of strain to increase the effectiveness of work hardening on the alloy.[53] Eglin Steel uses a combination of over a dozen different elements in varying amounts to create a relatively low-cost metal for use in bunker buster weapons. Hadfield steel (after Sir Robert Hadfield) or manganese steel contains 12–14% manganese which when abraded forms an incredibly hard skin which resists wearing. Examples include tank tracks, bulldozer blade edges and cutting blades on the jaws of life.[54]
Most of the more commonly used steel alloys are categorized into various grades by standards organizations. For example, the Society of Automotive Engineers has a series of grades defining many types of steel.[55] The American Society for Testing and Materials has a separate set of standards, which define alloys such as A36 steel, the most commonly used structural steel in the United States.[56]
Though not an alloy, galvanized steel is a commonly used variety of steel which has been hot-dipped or electroplated in zinc for protection against rust.[57]
Iron and steel are used widely in the construction of roads, railways, other infrastructure, appliances, and buildings. Most large modern structures, such as stadiums and skyscrapers, bridges, and airports, are supported by a steel skeleton. Even those with a concrete structure will employ steel for reinforcing. In addition, it sees widespread use in major appliances and cars. Despite growth in usage of aluminium, it is still the main material for car bodies. Steel is used in a variety of other construction materials, such as bolts, nails, and screws.[58] Other common applications include shipbuilding, pipeline transport, mining, offshore construction, aerospace, white goods (e.g. washing machines), heavy equipment such as bulldozers, office furniture, steel wool, tools, and armour in the form of personal vests or vehicle armour (better known as rolled homogeneous armour in this role). Steel was the metal of choice for sculptor Jim Gary and a frequent choice for sculpture by many other modern sculptors.
Before the introduction of the Bessemer process and other modern production techniques, steel was expensive and was only used where no cheaper alternative existed, particularly for the cutting edge of knives, razors, swords, and other items where a hard, sharp edge was needed. It was also used for springs, including those used in clocks and watches.[36] With the advent of speedier and thriftier production methods, steel has been easier to obtain and much cheaper. It has replaced wrought iron for a multitude of purposes. However, the availability of plastics in the latter part of the 20th century allowed these materials to replace steel in some applications due to their lower cost and weight.[59]
Steel manufactured after World War II became contaminated with radionuclides due to nuclear weapons testing. Low-background steel, steel manufactured prior to 1945, is used for certain radiation-sensitive applications such as Geiger counters and radiation shielding.
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